Greenhouse gases in the atmosphere
The greenhouse effect was discovered by Joseph Fourier in 1824 and was first investigated quantitatively by Svante Arrhenius in 1896. It is the process by which absorption and emission of infrared radiation by atmospheric gases warms a planet’s atmosphere and surface.
Existence of the greenhouse effect as such is not disputed. Naturally occurring greenhouse gases have a mean warming effect of about 33 °C (59 °F), without which Earth would be uninhabitable. The debate centers on how the strength of the greenhouse effect is changed when human activity increases the atmospheric concentrations of some greenhouse gases.
On Earth, the major greenhouse gases are water vapor, which causes about 36–70% of the greenhouse effect (not including clouds); carbon dioxide (CO2), which causes 9–26%; methane (CH4), which causes 4–9%; and ozone, which causes 3–7%. Some other naturally occurring gases contribute very small fractions of the greenhouse effect; one of these, nitrous oxide (N2O), is increasing in concentration owing to human activity such as agriculture. The atmospheric concentrations of CO2 and methane have increased by 31% and 149% respectively above pre-industrial levels since 1750. These levels are considerably higher than at any time during the last 650,000 years, the period for which reliable data has been extracted from ice cores. From less direct geological evidence it is believed that CO2 values this high were last attained 20 million years ago. Fossil fuel burning has produced about three-quarters of the increase in CO2 from human activity over the past 20 years. Most of the rest is due to land-use change, in particular deforestation.
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